The explosive reaction of baking soda and vinegar is an example of what happens when acids and bases mix.

Video segment. Assistance may be required. Watch the video below. Watch closely for the formulas of vinegar (acetic acid) and baking soda (sodium bicarbonate) and determine if the formulas fit Arrhenius’ definition of acids and bases. Answer the questions that follow.

Source: Chemistry Classics: Acid/Base - Vinegar (Acetic Acid) and Baking Soda (Sodium Bicarbonate), petgraveyard, YouTube


  1. The formula for acetic acid is HC2H3O2. Explain whether or not it meets the Arrhenius definition of an acid.
    Interactive popup. Assistance may be required. Check Your Answer Yes, acetic acid meets the definition of an Arrhenius acid, because when it dissolves in water, it breaks apart into H+ and C2H3O2- ions.Close Pop Up
  2. The formula for sodium bicarbonate is NaHCO3. Explain whether or not it meets the Arrhenius definition for a base.
    Interactive popup. Assistance may be required. Check Your Answer No, sodium bicarbonate does not meet the definition of an Arrhenius base, because when sodium bicarbonate dissolves in water, it breaks apart into Na+ and HCO3- ions; thus it doesn’t increase the concentration of hydroxide ions in the solution. Close Pop Up

Sodium bicarbonate is just one example of a substance that has many properties of a base, but it doesn’t contain OH- ions. (It turns red litmus paper blue and neutralizes acids.) Therefore, a new definition was needed that would include substances that acted like acids and bases but didn’t necessarily have hydrogen or hydroxide ions in them.

picture of Johannes Bronsted

Two scientists, Johannes Bronsted and Thomas Lowry, working separately both developed the same idea: acids and bases could instead be defined as proton donors or acceptors. (Remember that the H+ can also be called a proton.)

picture of Thomas Lowry

Bronsted-Lowry definition of acids and bases

Interactive exercise. Assistance may be required. Determine the acid and base in each reaction below.

Notice that water can act as a Bronsted-Lowry acid or an Bronsted-Lowry base. A substance that can act as an acid or a base is called amphoteric.


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